Below are the Exploits available to Rogues. If an Exploit has a prerequisite, like a minimum Ability Score or Rogue level, you can learn it at the same time you meet the prerequisites.
1st-Degree Exploits
Exploits of the 1st-degree are minor techniques slightly more complicated than swinging a weapon. They can be learned by Rogues with modest training and have no level prerequisite
2nd-Degree Exploits
Exploits of this degree represent the absolute peak of roguish skill that is achievable without dedicated training. 2nd-degree Exploits can be learned by any Rogue of 5th level or higher.
3rd-Degree Exploits
These Exploits are masterful acts of subterfuge and skill, and can only be learned by Rogues of 9th level or higher. Each of these Exploits can only be used once per short or long rest.
4th-Degree Exploits
Exploits of this degree are masterful skills that can only be learned by Rogues of 13th level or higher, and each of these Exploits can only be used once per short or long rest.
5th-Degree Exploits
Exploits of the 5th-degree are devious feats that rival deeds of the most cunning tricksters and archfey. These Exploits can only be learned by Rogues of 17th level or higher, and each 5th-degree Exploit you know can be used once per long rest.